Provenance And Source Area Weathering Of Sandstones From The Tarkwaian Group At The Northeastern Extent Of The Paleoproterozoic Ashanti Belt, Ghana: Constraints From Petrography And Geochemistry.

Abstract

An integrated geochemical and petrographic study was conducted on the Paleoproterozoic sandstones of the Tarkwaian Group exposed at the northeastern extent of the Ashanti Belt, Ghana. Recognizing the economic importance of the Tarkwaian Group, particularly owing to its extensive gold deposits, the primary objective was to investigate the provenance, tectonic setting, and crustal evolution of the Tarkwaian Group. The dominant quartz (polycrystalline and monocrystalline), together with minor muscovite, feldspar, hematite, and lithic fragments, characterize the sandstones and thus, the sandstones are classified as sublitharenite, and lith icsubarkose. Based on mineralogical composition and major element content, the sandstones can be classified as litharenite, sublitharenite, and minor greywacke. The high values of SiO2/Al2O3 (average: 12.74), relatively moderate values of K2O/NaO2 (average: 1.42), and high quartz content (average: 88%) suggest that the sedi ments are compositionally sub-mature to mature. The sandstones likely underwent low to moderate levels of sedimentary sorting and recycling owing to angular to sub-rounded grains and moderate Zr/Sc and Th/Sc values. The high Chemical Index of Alteration (CIA) signature (average: 76.79 wt%), Plagioclase Index of Alteration (PIA) values (average: 90.13 wt%), and Index of Compositional Variability (ICV) (average: 0.61 wt%) suggest moderate to intense chemical weathering within the region of origin. Overall, the mineralogical and geochemical features of the sandstones, such as a high proportion of quartz and feldspar, and elevated concentrations of elements such as Zr, Sc and Th, and moderate to high ratios of Al2O3/TiO2 and La/Sc indicate that they were likely sourced from felsic to intermediate igneous rocks and deposited in an active continental margin such as magmatic arc setting.