High-performance symmetric electrochemical capacitor based on graphene foam and nanostructured manganese oxide

Abstract

We have fabricated a symmetric electrochemical capacitor with high energy and power densities based on a composite of graphene foam (GF) with ∼80 wt% of manganese oxide (MnO2) deposited by hydrothermal synthesis. Raman spectroscopy and X-ray diffraction measurements showed the presence of nanocrystalline MnO2 on the GF while scanning and transmission electron microscopies showed needle-like manganese oxide coated and anchored onto the surface of graphene. Electrochemical measurements of the composite electrode gave a specific capacitance of 240 Fg−1 at a current density of 0.1 Ag−1 for symmetric supercapacitors using a two-electrode configuration. A maximum energy density of 8.3 Whkg−1 was obtained, with a power density of 20 kWkg−1 and no capacitance loss after 1000 cycles. GF is excellent support for pseudo-capacitive oxide materials such as MnO2, and the composite electrode provided a high energy density due to a combination of double-layer and redox capacitance mechanisms.