Synthesis, characterization and coordination chemistry of (pyrazolylphosphinite)palladium(II) complexes
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Date
2018-02
Journal Title
Journal ISSN
Volume Title
Publisher
Inorganica Chimica Acta
Abstract
Pyrazolylethylphosphinite compounds, L1 (2-(3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenlyphosphinite) and L2 (2-(3,5-di-tert-butyl-1H-pyrazol-yl)ethyldiphenylphosphinite) were reacted with the palladium(II) precursors [PdCl(CH3)(COD)] and [PdCl2(NCCH3)2] resulted in the formation of five novel complexes, produced from disproportionation reaction and have very interesting coordination chemistry. The results further emphasize the coordination versatility of pyrazolylphosphinite ligands towards palladium(II) metal centres.
Description
Keywords
Pyrazolylphosphinite, Palladium, Coordination, Disproportionation