Enhanced electrolyte performance by adopting Zwitterionic lithium-silica sulfobetaine silane as electrolyte additive for lithium-ion batteries
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Date
2019-12-25
Authors
Hamenu, L.
Phiri, I.
Bon, C.Y.
Mwemezi, M.
Madzvamuse, A.
Park, J.H.
Lee, K,S.
Ko, J.M.
Lu, Y.
Journal Title
Journal ISSN
Volume Title
Publisher
Materials Chemistry and Physics
Abstract
Zwitterionic lithium-silica sulfobetaine silane is fabricated by first synthesizing zwitterion sulfobetaine silane, grafting it onto hydrophilic silica to form silica sulfobetaine silane, and then lithiating the silica sulfobetaine silane. The resultant lithium-silica sulfobetaine silane additive is used as a liquid electrolyte additive in lithium-ion batteries with varying weight percentages in 1 M LiPF6 (ethylene carbonate/dimethyl carbonate ¼ 1:1). The electrolytes with the lithium-silica sulfobetaine silane shows higher ionic conductivities (1.92 × 10-2 S cm-1 at RT and 1.62 × 10-3 S cm-1 at -20 oC) and greater electrochemical stability (anodic limit at ~5.5 V vs. Li/Liþ) than the pure electrolyte (anodic limit at ~4.6 V vs. Li/Liþ). The discharge capacity of the lithium nickel cobalt manganese oxide/graphite cell is improved at higher C-rates with the addition of lithium-silica sulfobetaine silane due to increased ionic conductivity. The lithium nickel cobalt manganese oxide/graphite cells with the lithium-silica sulfobetaine silane additive also show stable cycling performance. These findings warrant the use of lithium-silica sulfobetaine silane as an electrolyte additive in lithium-ion batteries.
Description
Research Article
Keywords
Silica, Zwitterion, Ionic conductivity, Solid electrolyte interface