Browsing by Author "Dubey, B."
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Item A preliminary assessment of consumer's exposure to organochlorine pesticides in fruits and vegetables and the potential health risk in Accra Metropolis, Ghana(Food Chemistry, 2011-10) Bempah, C.K.; Donkor, A.; Yeboah, P.O.; Dubey, B.; Osei-Fosu, P.Accra Metropolis is the major recipient of agricultural produce in Ghana, with almost the entire population depending on rural agricultural activities for subsistence. To increase agricultural produce, various forms of pesticides are normally used in fruits and vegetable farming. The consequence is that several cases of pesticide poisoning have been observed. In this preliminary study, a field survey was carried out to assess the knowledge, attitudes, and peoples' perception concerning the use of pesticides by farmers in fruit production. The residual concentrations of selected pesticides in pawpaw, imported apples and tomato samples and the potential health risks associated with the exposure to these pesticides were also assessed. The field survey data indicated that more than 70% of the participants reported one or more poisoning upon fruits consumption resulting in pesticide-related illnesses. Pesticide residues in the various environmental samples were determined by gas chromatography with electron capture detector (GC-ECD). The results showed that, the levels of pesticide residues varied from <0.01 μg/g to as high as 0.11 μg/g depending on the pesticide monitored. The analysis of health risk estimates revealed heptachlor, heptachlor epoxide, endrin aldehyde, and endrin ketone levels exceeded the reference dose, suggesting a great potential for systemic toxicity in children considered the most vulnerable population subgroup. Lastly, the public is in the know of pesticide residues in fruits and calls for the curtailing of pesticide use on fruits and vegetable production via educational programmes for farmers on control and safer use of pesticides. © 2011 Elsevier Ltd. All rights reserved.Item Public Perception of E-Waste Management and Disposal Practices in Accra Metropolis, Ghana(Science and Development, 2017) Owusu, G.; Donkor, A.; Ziwu, C.; Nyarko, S.; Bonzongo, J.; Dubey, B.; Asante, I.; Nyame, F.The electrical/electronic industry is one of the fastest growing sectors in the world today. The increasing demand for newer electrical/electronic equipment and the shorter lifespan of these products leads to the generation of large volumes of e-wastes (electrical and electronic wastes) in the environment. Unlike the developed nations, there is lack of public awareness and proper legislation to effectively manage these wastes in most developing nations, including Ghana. In this study, a survey was carried out on 800 respondents to determine their knowledge of e-waste management practices and the effects on humans and the environment. The results generally revealed a low level of awareness, with most participants showing little or no interest in their environment. The majority of respondents identified reselling and recycling of used electrical and electronic equipment (UEEE) as the most appropriate and safe disposal methods. There was a correlation between level of education and knowledge of: (i) toxic chemicals in e-waste, (ii) human health and environmental impact and (iii) disposal methods for e-waste using a Chi-square test, a fact emphasized by Principal Component Analysis (PCA). Thus, there is the need for programmes to educate and create general awareness for this class of wastes as a potential source of pollutants.Item Validation of QuEChERS method for the determination of 36 pesticide residues in fruits and vegetables from Ghana, using gas chromatography with electron capture and pulsed flame photometric detectors(Journal of Environmental Science and Health - Part B Pesticides, Food Contaminants, and Agricultural Wastes, 2015-06) Donkor, A.; Osei-Fosu, P.; Nyarko, S.; Kingsford-Adaboh, R.; Dubey, B.; Asante, I.In this study, “Quick, Easy, Cheap, Effective, Rugged and Safe” ‘QuEChERS’ method was modified for the determination of 36 pesticides fortified at (0.01–1.0) mg kg−1 in three vegetables and a fruit (lettuce, carrot, tomatoes and pineapples respectively) from Ghana. The method involved extraction with acetonitrile, phase separation with primary secondary amine and magnesium sulfate; the final injection solution was reconstituted in ethyl acetate. Organochlorine and synthetic pyrethroids residues were detected with electron capture detector whereas organophosphorus, pulsed flame photometric detector was used. The recoveries at different concentration levels (0.01, 0.1 and 1.0 mg kg−1) were in the range of 83% and 93% with relative standard deviation ranging from 2% to 10% (n = 5) and the coefficient of determination (R2) was greater than 0.99 for all the 36 pesticides. The method was successfully tested on 120 real samples from Accra markets and this proved to be useful for monitoring purposes particularly in laboratories that have no gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry. © 2015, Copyright © Taylor & Francis Group, LLC.