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UGSpace is the institutional repository of the University of Ghana. UGSpace is an open access electronic archive for the collection, preservation and distribution of digital materials.

  • facilitate the deposit of digital content of a scholarly or heritage nature
  • and ultimately share, preserve and promote the intellectual output of the University in a managed environment.
 

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Defining ‘Smart Rural’ in the Framework of Regional Digitalisation
(IST-Africa 2021 Conference Proceedings, 2021) Lindblom, P.; Kolog , E.A.; Nygren, E.; Sutinen, E.
In this paper, we explored how a smart development framework could be harnessed for enhancing small and medium enterprise (SME) activities in rural communities. With this aim, this study considered and compared the landscape of the SME ecosystems in Ghana and Finland. Alongside the deprived countryside or remote work context, it has become clear that contemporary digital platforms and collaborative media represent an integral part of smart development. In addition, remote working possibilities help tackle challenging times or even a state of emergency, such as the ongoing COVID-19 crisis. We created our Smart rural development model (SRDm) to facilitate the digital transformation of SMEs and strategies in peripheral settings. Our SRDm was developed from the exploration of smart development literature in regional settings, and filtering numerous initiatives utilutilizedhin digitalization SME development context. The key target groups who can benefit from our research endeavor are the various strategic development organizations, financing authorities, and of course regional stakeholders, policymakers, business clusters, SMEs, and individuals.
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Institutions and African Economic Development
(Working Paper, 2022) Fosu, A.K.
In light of the increasing importance of institutions in economic development and Africa’s desire to catch up, the present paper provides an account of this crucial subject, ‘Institutions and African Economic Development. First, adopting the usual definition of ‘institutions’ as ‘rules of the game’, the paper shows that improvements in economic institutions, such as economic freedom, had begun by the early 1990s, and accelerated about the mid-1990s, consistent with observed improvements in economic and development outcomes. Also improved are measures of political institutions: an index of electoral competitiveness, constraint on the executive branch of government, and polity 2 as an indicator of the level of democracy, beginning in the late 1980s or early 1990s. Second, based primarily on a review of the extant literature, the paper observes that these improvements in the measures of economic and political institutions are positively associated with the increasing economic development in Africa. Third, indicators of institutional instability, measured by the frequency of civil wars and the incidence of coups d’etat, have been diminishing since the early 1990s, with implications for improved growth and human development. Fourth, some evidence is provided in support of the notion that African countries with better performance on institutional quality during the period of growth resurgence have also exhibited greater progress in poverty reduction. Finally, the paper concludes by flagging the potential risk of African countries backtracking on their respective trajectories toward achieving the democratic consolidation required to sustain the gains in growth and development.
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Ensemble learning prediction of transmittance at different wavenumbers in natural hydroxyapatite
(Scientific African, 2020) Okafor, E.; Dodoo-Arhin, D.; Obada, D.O.
Material engineering-based research has often relied so much on tedious human exper iments for generating specific engineering properties with a major draw-back of high time demand that can span between an hour and days. Hence to deviate from the usual paradigm, we provide an alternative approach which employs artificial intelligence (AI) based ensemble learning methods for predicting the degree of transmittance for a range of wavenumbers of infrared radiation through hydroxyapatite (HAp) samples. The effective samples (transmittance and wavenumber) were passed as input to the predictive systems. For this, we trained two ensemble learning methods: Extreme Gradient Boosting (XGBoost) and Random Forest on variants of HAp (density and time variations), while considering a fixed amount of 10,000 base estimators. The results show that Random Forest marginally outperforms the XGBoost in the testing phase but requires a much longer computing time. However, XGBoost is much faster than the Random Forest. Furthermore, the examined en semble learning models yielded a coefficient of determination (R2 > 0.997): which are in close agreement with experimental data, depicting an excellent generalization capacity. Additionally, the examined ensemble learning models showed a significant ≥ 99.83% de crease in computational complexity relative to the time spent when generating the exper imental data. Overall, the use of ensemble learning models is very important for validating material engineering properties
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Photocatalytic degradation of Rhodamine dyes using zinc oxide nanoparticles
(Materials Today: Proceedings, 2020) Dodoo-Arhin, D.; Asiedu, T.; Agyei-Tuffour, B.; et al.
This paper presents the synthesis of nanocrystalline zinc oxide (ZnO) particles via the sol-gel method using zinc acetate as a precursor. The calcination temperature of the ZnO was varied to determine its effect on particle size. The resultant samples were characterized using X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), UltraViolet–visible Spectroscopy (UV–Vis) and Scanning Electron Microscopy (SEM). Nanocrystalline wurtzite ZnO particles with crystallite sizes ranging from 16 nm to 30 nm were produced. The Energy Band gap of the synthesized zinc oxide nanoparticles decreased with increasing calcination temperature and crystallite size. SEM Micrographs showed rice-like microstructure morphology of ZnO nanoparticles. The usage of the ZnO nanoparticles as a photocatalyst was also explored in the degradation of Rhodamine B dye using UV light, with particular attention paid to the effect of particle size and catalyst load on the degradation efficiency of the dyes. The nanoparticles calcined at 400 C with a crystallite size of 16 nm resulted in the highest degradation efficiency of 95.41% when 0.2 g catalyst loading was applied. 2019 Elsevier Ltd. All rights reserved. Selection and peer review under the responsibility of the scientific committee of the International Symposium on Nanostructured, Nanoengineered, and Advanced Materials
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The physico-mechanical influence of dehydroxylized activated local kaolin: A supplementary cementitious material for construction applications
(Case Studies in Construction Materials, 2019) Marfo, K.K.; Dodoo-Arhin, D.; Agyei-Tuffou, B.; et al.
This work presents the effect of partially replacing metakaolin with Portland limestone cement to produce mortars for construction. Teleku Bokazo kaolin was explored as an SCM for the production of mortars. The hydration product between Portland limestone and metakaolin was studied. The kaolin was heat treated to form metakaolin and partially used to replace Portland limestone cement (PLC) in mortars to explore the optimum replacement and its mechanical and durability effect. The samples were characterized using X-ray diffraction (XRD) for phases and crystallinity of the kaolin. Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM) gave information on the functional groups formed during the hydration and structure and surface morphology respectively. The pastes and mortars produced were subjected to setting time, water absorption, flexure, and compression strength tests. The mechanical properties were observed to increase with increasing metakaolin replacements. Therefore, from the results obtained, it is suggested that a 20 % replacement of Portland limestone cement with Teleku Bokazzo metakaolin can be very suitable for construction applications.
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Hydroxyapatite ceramics prepared from two natural sources by direct thermal conversion: From material processing to mechanical measurements
(Materials Today: Proceedings, 2020) Akpan, E.S.; Dodoo-Arhin, D.; Dauda, M.; et al.
In this study, hydroxyapatite (HAp) was extracted from catfish bones (CB) and non-separated animal bones (NB). The bioceramic samples were prepared by a facile synthesis route and the representative scaffolds were prepared by cold compaction and sintered at 900 C, 1000 C, and 1100 C. To evaluate the properties of the produced HAp, X-ray diffraction (XRD) and Fourier Transform Spectroscopy (FT IR) analyses were carried out. The evaluation of the hardness of the representative bio-derived scaffolds was experimentally conducted while the fracture toughness and brittleness index were obtained by calculation using the hardness test parameters. The experimental data showed that as temperature increased up to 1000 C for CB, there was a consequential increase in hardness, while for NB, hardness values reduced throughout the sintering regimes. These gradients in mechanical measurements are ascribed to phase changes during heat treatment. 2020 The Authors. Published by Elsevier Ltd. This is an open-access article under the CC BY-NC-ND license (https://creativecommons.org/licenses/by nc-nd/4.0). Selection and Review under the responsibility of the scientific committee of the International Conference & Exposition on Mechanical, Material and Manufacturing Technology
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Modified nanostructured titania photocatalysts for aquatic disinfection applications
(Materials Today: Proceedings, 2020) Dodoo-Arhin, D.; Bowen-Dodoo, E.; Agyei-Tuffour, B.; et al.
According to SDG 6, everyone on earth should have access to safe and affordable drinking water. In sharing water-treatment technologies that lead to accomplishing this goal, it is imperative to devise ways of removing microbial contaminants such as E. coli from drinking water, especially in resource-limited settings that lack centralized water supply systems. One of the approaches is bacterial disinfection of water at the point of use. In this study, the bactericidal effects of the photocatalysis of titanium dioxide-based nanoparticles under UV and visible light are explored. Pristine and silver doped nanostructured mesoporous titanium dioxide (Ag-TiO2, TiO2) particles with high specific surface area and average crystallite domain size of 7.0–7.5 nm were prepared using the simple and cost-effective sol-gel technique followed by thermal treatment. The addition of Ag+ ions during the hydrolysis/condensation of the Ti(IV) molecular precursor led to the homogeneous dispersion of the Ag+ cations on the titania matrix. The As-prepared nanoparticles were characterized using X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area analysis, Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), thermogravimetry, Fourier Transform Infra-Red (FTIR), and Raman Spectroscopy. X-ray diffraction, FTIR, and Raman spectroscopy confirmed that the crystalline structure of the TiO2 matrix corresponds to the anatase polymorph; however, the presence of the dopant led to an increase in the system disorder due to the rise in the concentration of oxygen vacancies. The As-prepared nanoparticles were used for Escherichia coli (E. coli) inactivation under dark and UV–visible light conditions. Under dark conditions, Ag-doped titania and pristine titania resulted in 95% and 64% E. coli population inactivity while under light conditions, 99% and 97% degradation respectively were observed. Taken together, these results demonstrate that, the synthesized TiO2 nanoparticles have promising applications in the light-mediated point-of-use inactivation of bacterial contaminants in water. 2019 Elsevier Ltd. All rights reserved. Selection and peer review under the responsibility of the scientific committee of the International Symposium on Nanostructured, Nanoengineered, and Advanced Materials.
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What influences cancer treatment service access in Ghana? A critical interpretive synthesis
(BMJ Open, 2022) Tuck, C.Z.; Aryeetey, R.N.O.; Akparibo, R.; et al.
Objectives Multiple social-cultural and contextual factors influence access to and acceptance of cancer treatment in Ghana. This research aimed to assess the existing literature on how these factors interplay and could be susceptible to local and national policy changes. Design This study uses a critical interpretive synthesis approach to review qualitative and quantitative evidence about access to adult cancer treatment services in Ghana, applying the socioecological model and candidacy framework. Results Our findings highlighted barriers to accessing cancer services within each level of the socioecological model (intrapersonal, interpersonal community, organizational and policy levels), which are dynamic and interacting, for example, community-level factors influenced individual perceptions and how they managed financial barriers. Evidence was lacking about determinants of treatment non-acceptance across all cancers and in the most vulnerable societal groups due to methodological limitations. Conclusions Future policy should prioritize multilevel approaches, for example, improving the quality and affordability of medical care while also providing collaboration with traditional and complementary care systems to refer patients. Research should seek to overcome methodological limitations to understand the determinants of accessing treatment in the most vulnerable populations.
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Seed quality and relative lignan profiles of sesame prospected from northern Ghana
(Heliyon, 2024) Sintim, H.O.
The sesame seed contains oil, protein, dietary fibre, and several minerals and it is also a store of lignans. Lignans are key selection factors for sesame quality due to their health, nutritive and market value. In Ghana sesame growers rely on wild or undocumented planting seeds which are of mixed colouration and its lignan content is ambiguous. The objective of this study was to segregate street sesame seeds into component colour fractions and subsequently evaluate the consistency of lignans in the seed fractions. Sesame seeds were collected from street vendors in northern Ghana and were segregated into seed fractions based on the pericarp colour. The viability of seed fractions stored at different temperatures (ambient, 5 ◦C, 0 ◦C) over time and lignan contents of single or bulk mixed seeds were verified. The collected seeds were of mixed colouration with approximately 4 % debris, 40 % white, 36 % cream, and 20 % dark coloured seeds by weight. The viability of the seeds was 67–85 % depending on pericarp colour. White seed fractions which had the highest proportion by weight had a significantly (p = 0.0275) higher viability (85 %) than the dark seeds which had the least viability (67 %). The seeds lost viability over time. However, seeds stored at 0 ◦C maintained a viability of 77 % at the fourth year. There were differences in the relative abundance of lignans for both bulk seeds and, single seeds with different pericarp colours. The most abundant occurring lignans in the seeds were sesamin, ses amolin and sesaminol and its downstream glucosides. The source of seed or pericarp colour was not predictive of seed viability or lignan composition. These findings provide baseline data on seed quality including an improved storability under cold environments. It also gives an insight into how mixed seeds of variable pericarp colours can have distinct characteristics. Although the mixed coloured seeds had no implications for varied quality including lignan content, the in ternational market for sesame requires that seeds are of consistent colour.
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Land Governance and Conflict in West Africa through Interdisciplinary Empirical Lenses
(Merian Institute for Advanced Studies in Africa (MIASA), 2024-09) Narh, P.; Doumbia, L.; Tounkara, A.; Ablo, A.D.
This working paper addresses the following central questions: (i) How does the commodification of land challenge distinctions between rural and urban spaces? (ii) What new forms of differentiation emerge from commodification, for example the alienation of land markets from land governance regimes? (iii) How does commodification help our understanding of the resilience of custom and egalitarianism? (iv) How useful are property rights frameworks, whether customary, statutory or new forms of tenure, for land management and sustainability? Four authors, members of the MIASA Interdisciplinary Fellow Group (IFG 6) on Land Governance, applied ethnographic and cross-sectional research methods to examine case studies in Ghana, Mali and Senegal. This research contributes to an understanding of the perceptions, discourses and practices relating to land commodification and conflicts, as well as the way in which endogenous perceptions of access to land in West Africa are expressed and adapt to changing circumstances.